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What is bismuth oxid?
The pure bismuth trioxide (nanopowder ) is classified into three types: a, b and d. A type is yellow monoclinics with relative density 8.9 melting point 825, which are soluble only in acid and insoluble both in water and in alkali. b type is bright yellow to orange tetragonal crystalline system, with relative density 8.55. melting point 860. Soluble in acid, but not water. Hydrogen and hydrocarbons can be used to reduce the material into metallic bismuth. The cubic fluorite structure of dBi2O3 makes it a unique material. The crystal lattice of d-Bi2O3 is void in 1/4, which gives it a high oxygen conductivity. Bismuth Oxide is mainly used for electronic ceramic powder materials. It can also be used as photoelectric materials. Bismuth is an essential additive in electronic ceramic materials. Its purity must be at least 99.15%. Main application objects include ceramic capacitors, zinc oxide varistors, and ferrite magnet materials.
The method for synthesis of bismuth dioxide
The aqueous sodium solution without carbon dioxide, which is a solution that contains no carbon dioxide in it, was mixed with the bismuth-nitrate solution at 80-90degC. During the precipitation procedure, the solution remains alkaline. A white, volume-swelling Bismuth Oxide Hydrate Bi(OH3) precipitates. The solution is heated, stirred and dehydrated to yellow bismuth trioxide. After decantation of water, filtering and a drying process, the final bismuth dioxide product is obtained.
A 0.1 mol/L Bismuth Nitrate Solution dissolved in 1 mole/L Nitric Acid (at 80 to90deg C.) was dropped into a 1.5 mol/L NaOH aqueous solution, without any carbon dioxide. During precipitation, the solution remains alkaline. The white volume-expanded bi(OH)3 bismuth oxide is precipitated, but it dehydrates and becomes light yellow bismuth trioxide after stirring in a warm solution. Wash 15 times in water without carbon dioxide or air, then filter and dry.
After melting the metal bismuth in the graphite-crucible, an arc will form between the electrode graphite and the metal’s surface. This arc will heat the metal and cause it to oxidize when oxygen is flowing. For a continuous supply of oxygen to the crucible, it should be kept in a large vessel and placed on agitator. The reaction is carried out at a temperature of 750-800degC and the b bismuth trioxide is generated quickly with a purity level of 99.8%. A high-temperature phase B-type product is obtained by quenching the product in water or a metal plate.
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